【公開日：2025.06.10】【最終更新日：2025.04.06】

課題データ / Project Data

課題番号 / Project Issue Number

24NM5248

利用課題名 / Title

Hierarchically porous materials for environmental applications.

利用した実施機関 / Support Institute

物質・材料研究機構 / NIMS

機関外・機関内の利用 / External or Internal Use

内部利用（ARIM事業参画者以外）/Internal Use (by non ARIM members)

技術領域 / Technology Area

【横断技術領域 / Cross-Technology Area】（主 / Main）計測・分析/Advanced Characterization（副 / Sub）物質・材料合成プロセス/Molecule & Material Synthesis

【重要技術領域 / Important Technology Area】（主 / Main）高度なデバイス機能の発現を可能とするマテリアル/Materials allowing high-level device functions to be performed（副 / Sub）次世代ナノスケールマテリアル/Next-generation nanoscale materials

キーワード / Keywords

Porous crystals, Near Infrared emitters, Singlet Oxygen Generators,電子顕微鏡/ Electronic microscope,核磁気共鳴/ Nuclear magnetic resonance,赤外・可視・紫外分光/ Infrared/visible/ultraviolet spectroscopy,X線回折/ X-ray diffraction,質量分析/ Mass spectrometry,核磁気共鳴/ Nuclear magnetic resonance, 質量分析/ Mass spectrometry,赤外・可視・紫外分光/ Infrared/visible/ultraviolet spectroscopy,センサ/ Sensor,ナノカーボン/ Nano carbon,ナノ多孔体/ Nanoporuous material

利用者と利用形態 / User and Support Type

利用者名（課題申請者）/ User Name (Project Applicant)

ヒル ジョナサン

所属名 / Affiliation

物質・材料研究機構

共同利用者氏名 / Names of Collaborators in Other Institutes Than Hub and Spoke Institutes

Dr. Mandeep K. Chahal

ARIM実施機関支援担当者 / Names of Collaborators in The Hub and Spoke Institutes

Dr. Yoshitaka Matsushita

利用形態 / Support Type

（主 / Main）機器利用/Equipment Utilization（副 / Sub）,技術補助/Technical Assistance

利用した主な設備 / Equipment Used in This Project

NM-002：LC-MS（Q-Exactive Plus）
NM-209：2波長Pilatus低温単結晶X線回折装置_NSC
NM-201：多環境場対応型X線単結晶構造解析装置
NM-211：高速・高感度型粉末X線回折装置_Cu_ASC_NS3
NM-222：蛍光分光計（Fluorolog-3）

報告書データ / Report

概要（目的・用途・実施内容）/ Abstract (Aim, Use Applications and Contents)

Macrocyclic compounds have been prepared for use in sensing devices. Other materials have been prepared as photosensitizers for singlet oxygen generation. Crystals structures were determined of the relevant materials.

実験 / Experimental

Compounds were prepared using organic synthesis methods, and the products were purified using chromatographic techniques. Crystals of the materials suitable for X-ray crystallography were grown by vapor diffusion or solvent layering. 

結果と考察 / Results and Discussion

New materials for incorporation into sensing devices were prepared and characterized for that purpose. Crystal structures of the molecules were determined. ESI-TOF MS was used to confirm the identities of the compounds. Optical properties of the compounds were investigated using fluorescence/phosphorescence emission spectrophotometry.

図・表・数式 / Figures, Tables and Equations

Fig. 1. Porous porphyrin for environmental applications.

その他・特記事項（参考文献・謝辞等） / Remarks(References and Acknowledgements)

Data will be published in due course.

成果発表・成果利用 / Publication and Patents

論文・プロシーディング（DOIのあるもの） / DOI (Publication and Proceedings)

口頭発表、ポスター発表および、その他の論文 / Oral Presentations etc.

特許 / Patents

特許出願件数 / Number of Patent Applications：0件
特許登録件数 / Number of Registered Patents：0件